By DAILY MAIL REPORTER
Wild outdoors: Angelina Jolie poses for a sultry new ad for Louis Vuitton photographed by Annie Leibovitz
She is regularly seen toting their exclusive bags and now Angelina Jolie has become the new face of luxury luggage designer Louis Vuitton.
The 35-year-old actress appears in a stunning new ad for the brand's 'Core Values' campaign in which she poses barefoot aboard a traditional wooden boat in Cambodia’s Siem Reap province in a photo taken by famed portrait photographer Annie Leibovitz.
Happy couple: Angelina joined her partner Brad Pitt at the première of his new film Tree Of Life last month
Angelina poses in her own clothes, with no make-up on with her long dark hair worn au natural and wavy.
In the picture she holds onto her own years-old monogrammed Alto bag, a style which is no longer in production.
Cambodia is a country close to the star's heart as it's where she adopted nine-year-old Maddox, her eldest son, from as a baby.
Big brood: The mother of six moves her family around the globe depending on where she is working
'People are not used to seeing Angelina in this situation,' Louis Vuitton’s executive vice president Pietro Beccari tells Women's Wear Daily.
'I like the fact that it’s a real moment.'
'This travel message we give through personal journeys is a fundamental one for the brand. This campaign is about a very special person and a very special journey.'
In typical Angelina style she also donated a portion of her earning from the campaign to charity.
Just last week her partner, Brad Pit, 47, donated $500,000 to a charity that is helping to rebuild his tornado ravaged home state of Missouri.
Their generous contribution to The Community Foundation of the Ozarks will go toward bringing the Joplin area back to life, which was recently destroyed by deadly twisters.